platinum for glass

=manufacturing =materials =composites

 

 

The strongest available materials today are fiber composites. If you want something with higher specific strength than steel, the cheapest and most common choice is glass fiber ("GF") composite.

The best carbon fiber ("CF") is stronger than GF, but it's much more expensive. There are also various polymer fibers, but they all have much lower compressive strength than GF and CF, because the molecules have weaker transverse strength so the fibers buckle.

M5 fiber is a polymer fiber with ~50% the compressive strength of CF, but it's very expensive. That's several times the compressive strength of Kevlar, which is still expensive, much more expensive than GF. Usually, the only reason to use polymer fibers instead of glass fiber is if you want fabric that bends easily rather than something with high compressive strength. (M5 fiber is made by an interesting route, with dihydroxyterephthalic acid coming from Claisen condensation of dimethyl succinate, but that certainly doesn't make it cheap.)

So, GF is the main fiber for composites, with >30x the annual production of carbon fiber, and there's no good alternative. The raw materials for GF are abundant, so that might seem fine, but there's a problem.

 

 

Glass fiber is made by extruding molten glass through small holes with bushings made of platinum alloy. Platinum is the only material that works for this; every refractory metal and simple ceramic was tried. It has a single surface layer of oxygen, which is able to match the oxygen patterns of molten glass, so glass wets it well, but it doesn't dissolve (much) in the molten glass to be surrounded by oxygen.

A small amount of platinum does dissolve in the glass, and platinum is now $29/g. Stronger glass compositions tend to require higher temperatures and dissolve more platinum; this is the main tradeoff between cost and performance. This application uses perhaps 10% of platinum today; the main use is currently catalytic converters for cars.

That amount of use isn't a problem, especially if some piston-engine cars are replaced by electric cars, but what if you want to start replacing steel and concrete with fiberglass? If GF production increased 10x, then platinum availability would be a major problem.

So, mine more platinum? That's not easy. Platinum is currently a byproduct of copper and nickel production. Mining platinum by itself would be very expensive, and if platinum prices go up 10x, then GF would also become more expensive.

This is a major reason why I bother spending any time thinking about high-strength polymer fibers despite them being generally much worse than GF and CF. But obviously, that's only a potential longer-term issue, and what we'll see in the short term is more GF production. Yes, theoretically some cheaper CF production process could be developed instead, but CF remains expensive despite large-scale production and fairly low profit margins, and polymer fibers have more potential routes to better cost-performance.

 

 


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